Meghan Markle is "green with envy" because Catherine has 12 portraits in the National Portrait Gallery's collection while she has none is speculation. There is no evidence to support this claim, and it is possible that Markle is not envious at all.
It is true that Catherine has more portraits in the National Portrait Gallery's collection than Meghan Markle. However, there are a number of reasons for this. First, Catherine has been a member of the royal family for much longer than Meghan Markle.
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Second, Catherine is the Duchess of Cambridge, which is a more senior title than Meghan Markle's title of Duchess of Sussex. Third, Catherine has been the subject of more public interest than Meghan Markle.
It is also worth noting that the National Portrait Gallery's collection includes portraits of many other royal women, including Queen Elizabeth II, Queen Victoria, and Princess Diana. Meghan Markle is not the only royal woman who does not have a portrait in the collection.
Ultimately, it is impossible to say for sure whether or not Meghan Markle is envious of Catherine's 12 portraits. However, there is no evidence to support the claim that she is. It is more likely that Markle is simply focused on her own life and her own family.